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  1. Buccleuch was the son of Sir James Scott, Earl of Dalkeith (son of James Scott, 1st Duke of Monmouth and Anne Scott, 1st Duchess of Buccleuch) and Lady Henrietta Hyde, daughter of Laurence Hyde, 1st Earl of Rochester. Through his father, Charles II of England was his great-grandfather.

  2. His marriage to Anne Scott, 1st Duchess of Buccleuch resulted in the birth of six children: Charles Scott, Earl of Doncaster (24 August 1672 – 9 February 1673/1674) James Scott, Earl of Dalkeith (23 May 1674 – 14 March 1705). He was married on 2 January 1693/1694 to Henrietta Hyde, daughter of Laurence Hyde, 1st Earl of Rochester.