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  1. Hace 2 días · married Infanta Maria Luisa of Spain (1745–1792), had issue. Grand Duke of Tuscany from 1765 (abdicated 1790), Holy Roman Emperor from 1790, Archduke of Austria, King of Hungary and King of Bohemia from 1790. 10: Archduchess Maria Carolina of Austria: 17 September 1748: 17 September 1748: died during birth. 11: Archduchess Maria ...