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  1. Maria Antonia of Naples and Sicily (14 December 1784 – 21 May 1806) was the youngest daughter of Ferdinand, King of Naples and Sicily, and Maria Carolina of Austria. As the wife of the future Ferdinand VII of Spain , then heir apparent to the Spanish throne, she held the title of Princess of Asturias .

  2. Isabella of Bourbon-Parma (Spanish: Isabel María Luisa Antonieta Fernanda Josefa Javiera Dominica Juana de Borbón-Parma, German: Isabella Maria Luise Antonia Ferdinanda Josepha Xaveria Dominika Johanna von Bourbon-Parma; 31 December 1741 – 27 November 1763) was a princess of Parma and infanta of Spain from the House of Bourbon-Parma as the daughter of Philip, Duke of Parma.

  3. Married Princess Maria Antonia of Naples and Sicily in 1802, no issue. Re-instated as King in 1813. Married Maria Isabel of Portugal in 1816, had issue. Married Maria Josepha Amalia of Saxony in 1819, no issue. Married Maria Christina of the Two Sicilies in 1829 and had issue, including the future Isabella II of Spain. Died in 1833.

  4. Maria Maximiliana Thekla Johanna Josepha of Austria (1827–1834), died in childhood. Maria Josepha Amalia Carlotta Giovanna (1828-1836), died in childhood. After Maria Anna's death at Pisa in 1832, her husband married Princess Maria Antonia of the Two Sicilies. Ancestry

  5. Princess Maria Luisa of Bourbon-Parma (Marie Louise Pia Theresa Anna Ferdinanda Francisca Antonia Margaret Josepha Carolina Blanche Lucia Apollonia; 17 January 1870 – 31 January 1899) was the eldest daughter of Robert I, the last reigning Duke of Parma.

  6. In 2003, Maria Pia was married to Prince Michel of Bourbon-Parma (1926–2018), son of Prince René of Bourbon-Parma and Princess Margaret of Denmark, whose marriage with Princess Yolande de Broglie-Revel had been annulled and with whom he has five dynastic children, also being the father of a child born out of wedlock in 1977, Amélie de Bourbon de Parme (wed in 2009 to Igor Bogdanoff).

  7. Dona Maria Manuela (15 October 1527 – 12 July 1545) was the eldest daughter and second child of King John III of Portugal and his wife Catherine of Austria. She was Princess of Asturias and Duchess of Milan as the first wife of the future Philip II of Spain , and Princess of Portugal as heir presumptive to the Portuguese throne between 1527 and 1535.